I actually have one of those multi-speed hubs and it has no documentation warning about only being able to plug certain speeds into certain places. In fact, I can move my empeg (the only 10Mbps device I have on that network) to any port and not have a problem. Now it's still possible that there's something like what you suggest going on behind the scenes, but, if so, it's totally transparent to the user.
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Bitt Faulk