It seems that there is the possibility of having it setup for multiple domains, you just cant be logged into more than one at a time. In the login drop-down box there used to be a few different domains. At login, I could choose what domain to log into. The problem is that when I changed over to a workgroup, it lost all of the domain options in the login box. Then when I went back into Network Identification to put it back to domain (so that I could access my cached profile) it would not allow me to enter the domain name. When I tried to enter the domain name, it just stated that it could not find the domain, and it would not allow me to change that property even though I had a cached profile for that domain.
I was able to temporarily fix my problem though. What I did was login locally as the Administrator and create a local account. Then, I copied the entire contents of the cached profile (C:/documents and settings/{username}/) to the newly created account profile. I rebooted and logged in as the new user, and everything looked just like it used too, before all this mess.
I realize however, that this is a very temporary fix, and that I need to get the domain account working properly asap. (when I can physically connect to the domain network) Any changes I make with the account will not be updated to my normal domain-enabled profile.
Why does this have to be so complicated?