The things for @Work in my config.ini are:
[Network]
;@Work DHCP=1
[hijack]
;@Work kftpd_control_port=0
;@Work khttpd_port=666
;@Work khttpd_basic=user1:pass1
;@Work khttpd_full=user2:pass2

After typing this in I went to double check if it was work mode cause I can use work mode at home cause my router has dhcp abilities. It wasnt that. it was fine, I was having a major blonde moment, I use winamp at home not WMP (Doh!) WMP doesnt work at home either, Ill install winamp at work and it will probobly be fine.